专利名称:Thermoset rigid rod molecular composite
system
发明人:Fred E. Arnold,Thaddeus E.
Helminiak,Donald R. Wiff,Loon S. Tan,Wen F.Hwang,Hoe Chuah
申请号:US07/307112申请日:19890202公开号:US04977223A公开日:19901211
摘要:Provided is a molecular composite comprising a rigid-rod aromatic heterocyclicpolymer, a flexible, coil-like thermoplastic polymer and a thermosetting polymer.
Also provided is a method for fabricating a molecular composite film or fiber whichcomprises the steps of forming a biphasic, stir opalescent solution of a rigid-rod aromaticheterocyclic polymer, a thermoplastic polymer, a thermosetting polymer and a solventwhich is common to the three polymers, adding solvent to the solution until the solutionbecomes isotropic and stir opalescence has ceased to determine the critical
concentration of polymers in the solvent, adding additional solvent to the solution sothat the polymer concentration is below the critical concentration, extruding the solutioninto a non-solvent for the polymers to form the desired film or fiber, drying the film orfiber and hot drawing the film or fiber at a temperature above the Tg of the
thermoplastic, but below the polymerization temperature (Tpoly) of the thermosettingresin.
申请人:THE UNITED STATE OF AMERICA AS REPRESENTED BY THE SECRETARY OF
THE AIR FORCE
代理人:Charles E. Bricker,Donald J. Singer
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